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Chalmette Refining, LLC, Chalmette

Releases of Nitric Oxide

LDEQ Incident Number
Incident Date
Point Source(s) Notes Amount of Release
81586

2006-08-23
LPG Compressor (K-9200)
LPG Compressor tripped, then went to #2 Flare
Cause: LPG Compressor tripped causing fuel system to overpressure

Followup: Yes

Notes: This is a verbal report; there is no letter - the usual type of report - in the files as a follow up though one is promised.
20.0 pounds
81586

2006-08-23
LPG Compressor (K-9200)
LPG Compressor tripped, then went to #2 Flare
Cause: LPG Compressor tripped causing fuel system to overpressure

Followup: Yes

Notes: This is a verbal report; there is no letter - the usual type of report - in the files as a follow up though one is promised.
20.0 pounds
84794

2005-12-24
Rich DGA Pump G-8291
Cause: Electrical supply malfunction caused the auto shutdown of the refinery Sulfur Recovery Unit Train 2. The shutdown resulted in routing of refinery acid gas to the flare system.

Followup: No

Notes: Operations were conducted in order to minimize emissions while maintaining a safe and orderly stabilization of refinery operations and restart of the impacted process unit. Repairs were made to applicable electrical equipment and SRU train 2 was restarted, ending the incident. The refinery has initiated an investigation into the cause of this incident. Based on the result of that investigation, appropriate measures will be taken in order to prevent a recurrence due to the same cause.
239.0 pounds
84745

2005-12-22
Sulfur Recovery Unit Train 2
Cause: instrument malfunction caused the automatic shutdown of the refinery sulfur recovery unit train 2, resulting in the routing of refinery acid gas to the flare system (No. 1)

Followup: No

Notes: Operations were conducted in order to minimize emissions while maintaining a safe and orderly stabilization of refinery operations and restart of the impacted process unit. Repairs were made to applicable instrumentation and SRU Train 2 was restarted, ending the incident. The refinery has initiated an investigation into the cause of this incident. Based on the result of that investigation, appropriate measures will be taken in order to prevent a recurrence due to the same cause.
888.0 pounds
84681

2005-12-19
Hydrocracker (HCU) Second Stage Make-up Hydrogen Compressor (K-2302)
Cause: Hydrocracker (HCU) compressor (K2302) alignment and unit conditions were causing a pressure safety valve to relieve refinery grid hydrogen to the flare.

Followup: No

Notes: A search located the source of excess flare gas. The situations which caused the PSV to relieve the flare were modified, ending the incident. Normal procedures for HCU startup will be reviewed in order to evaluate line-ups that could result in flaring and modify them if appropriate.
79.0 pounds
05-BB005-297

2005-12-18
Coker 2 Wet Gas Compressor K8101
Cause: Compressor went into high alarm for high vibration. It was determined that the vibration probe had provided a false alarm due to a faulty connection.

Followup: No

Notes: In order to avoid equipment damage and associated emissions, refinery personnel shut down the machine. The vibration probe was repaired and the machine was put back in service, ending the incident. Instrument and electrical connections directly relatedto K8101 were double checked for proper connections in order to avoid a recurrence due to the same root cause.
254.0 pounds
84474

2005-12-12
Wet Gas Compressor K8101
Cause:

Followup: No

Notes: Machine restarted. Below reportable quantities
6.0 pounds
84328

2005-12-05
Operating Sulfur Recovery Unity
Cause: Loss of power triggered upset of refinery and shutdown of the refinery's operating sulfur recovery unit.

Followup: No

Notes: Operations were conducted in order to minimize emissions while maintaining a safe and orderly stabilization of refinery operation and restart of some refinery process units. Refinery Management has met with Entergy to stress the impact of this incident and request that appropriate measures be taken in order to prevent a recurrence.
2,070.0 pounds
84247

2005-12-02
Pressure Safety Value
Cause: Unexpected blockage caused backpressure in the unit causing a PSV to relieve to the flare.

Followup: No

Notes: A search located the source of excess flare gas. The PSV which relieved to the flare was isolated, ending the incident.
57.0 pounds
84073

2005-11-23
No. 2 Coker Wet Gas Compressor
Cause: The wet gas compressor shut down due to the axial thrust alarm, resulting in emissions from the No. 1 Flare. Following investigation, refinery personnel believe the Wet Gas Compressor shut down due to a momentary loss of lube oil.

Followup: No

Notes: In an effort to stop the release, the compressor was restarted, but the alarm remained. Following determination by refinery personnel that maintenance was required on the compressor, K-8101 was taken out of service and sent out for repair. A variance was applied for with the LDEQ to authorize the emissions associated with the compressor maintenance. The variance was approved on November 29, 2005, ending this release.
2,490.0 pounds
81795

2005-08-27
FCC Debutanizer Overhead Condenser
Cause: Condenser overpressured due to a failure with a pressure controller, resulting in flaring and a small ground fire.

Followup: No

Notes: For the FCC, the tower was returned to normal pressure and the pressure transmitter on the overhead condenser was repaired. The small ground fire was extinguished.
74.0 pounds
05-BB005-267

2005-08-27
Plant Facility
Cause: Shutdown in advance of Katrina. Emissions resulted from gas flaring, fuel gas quality changes, and standby operation modes necessitated by the shutdown.

Followup: No

Notes: Substance released to atmosphere through the refinery. For the refinery shutdown, operations were conducted in order to minimize emissions while maintaining a safe and orderly shutdown.
467.0 pounds
81016

2005-08-05
Coker 1 Heavy Gas Oil pump G2804 problem led to release at the No. 2 Flare
Cause: Seal on coker 1 Heavy Gas Oil pump G2804 failed, causing a localized fire at the pump. Caused coker 1 wet gas compressor K2800 to shutdown due to high drum level. Flare to no. 2.

Followup: No

Notes: Unit throughput was reduced to minimum and attempts to restart required process equipment were made. Unit feed was changed from sour (high H2S concentrations) to sweet (lower H2S concentrations) to minimize emissions. The unit was stabilized and the flaring ceased.
68.0 pounds
80685

2005-08-03
No information given
Cause:

Followup: No

Notes: BELOW REPORTABLE QUANTITIES
80865

2005-07-22
Hydrocracker
Cause: Hydrocracker overpressured

Followup: No

Notes: BELOW REPORTABLE QUANTITIES
3.0 pounds
80590

2005-07-18
No information given
Cause:

Followup: No

Notes: BELOW REPORTABLE QUANTITIES
4.0 pounds
05-BB005-243

2005-07-17
Wet Gas Compressor K 2800 shut down and went to the No. 2 Flare
Cause: coker 1 wet gas compressor (K2800) shut down due to high knock-out drum level. Resulted in flaring of process gasses until it could be re-started.

Followup: No

Notes: Process adjustments were made in order to minimize the likelihood of fractionators liquid carryover and high knock-out level, prior to the re-start of the compressor. K2800 was re-started, ending the incident
22.0 pounds
80533

2005-07-15
Cat feed hyrdrotreater unit problem caused release to the No. 2 Flare
Cause: Cat feed hydrotreater (CFHT) developed a leak due to a failure in the piping. The unit was shut down in order to eliminate the lead and safely conduct repairs. Vented through flare 2

Followup: No

Notes: Cat Feed hydrotreater (CFHT) was shut down and hydrogen and process gas vented to the refinery flare system. Operations were conducted in order to minimize emissions while maintaining a safe and orderly shutdown and restart of the CFHT
127.0 pounds
80502

2005-07-13
Transformer power outage - emitted at No. 2 Flare
Cause: Loss of a refinery power transformer resulted in unplanned shut-down of coker 1, resulting in flaring to no. 2

Followup: No

Notes: backup transformer was placed in service to replace the one that failed.
266.0 pounds
80322

2005-07-06
No information given
Cause:

Followup: No

Notes: Tropical storm caused power failure
167.0 pounds
80288

2005-07-04
Hydrocracker Light Ends Plant Butane Splitter Tower & LEP Depropanizer
Cause: LEP Butane Splitter Tower began to overpressure. Moves in operating temperature and pressure on LEP Depropanizer, actuated by the refinery advanced controls system, allowed propane to exit via Depropanizer Bottoms, to the Butane Splitter, which is not designed to off-gas light materials such as propane. Personnel mode moves to lower tower pressure, including the venting of Propane in the Butane Splitter, to the refinery flare system in order to lower the pressure of the tower to safe levels.

Followup: No

Notes: Cooler back flushing was conducted in order to ensure that maximum cooling was available. Refinery personnel made operational adjustments that ended the incident. Various level controllers and analyzers associated with the LEP Depropanizer and Butane Splitter were checked for proper operation. The refinery has initiated an investigation into the cause of this incident.
19.0 pounds
79977

2005-06-20
No. 2 Flare
Cause: The LPG compressor tripped; the alarm panel showed a high suction drum level. Upon investigation no high drum was detected. The machine was restarted and tripped again on a high level indication. A this time the high level alarm was calibrated by the operators and again restarted.

Followup: No

Notes: The level in the suction drum was checked and upon tripping a second time the operators checked the high level shutdowm switch chamber for liquid. Finding none, the machine was restarted.
11.0 pounds
79529

2005-06-02
Hydrocracker Light Ends Plant Butane Splitter Tower
Cause: The Hydrocracker Light Ends Plant (LEP) Butane Splitter Tower began to overpressure; moves in operating temperature and pressure on the LEP Depropanizer, actuated by the refinery advanced system controls system, allowed propane to exit via Depropanizer Bottoms, to the Butane Splitter, which is not designed to off-gas light materials such as propane.

Followup: No

Notes: Cooler back flushing was conducted in order to ensure that maximum cooling was available. Refinery personnel made operational adjustments that ended the incident. Various level controllers and analyzers associated with the Lep Depropanizer and Butane Splitter were checked for proper operation.
11.0 pounds
79189

2005-05-19
Hydrocracker Light Ends Plant - Butane Splitter Tower
Cause: : Excess feed to the Depropanizer Tower caused overpressure

Followup: No

Notes: moves to reduce temperature and pressure were made in effort to prevent the depressurization of the Butane Splitter to the refinery flare system. Cooler back flushing was conducted in order to ensure that maximum cooling was available, heater firing wasreduced in order to reduce tower temperatures and pressures.
77.0 pounds
05-BB005-210

2005-05-11
K3304
Cause: Leak on the Hydrodesulphurization (HDS) Unit Off0gas Compressor K-3304

Followup: No

Notes: Sweet streams (lower Sulfur content) were routed to the flare to minimize sour gas flaring. Process unit output was adjusted in order to minimize the total amount of waste gas being sent to the flare.
64.0 pounds
78900

2005-05-08
K-4301
Cause: After starting the propane compressor the first and second stage releif valves opened to the flare.

Followup: No

Notes: Below reportable quantities; initial report said 12 lbs had been released.
5.0 pounds
05-BB005-206

2005-05-07
No information given
Cause:

Followup: No

Notes: Below reportable quantities
5.0 pounds
78541

2005-04-26
Sulfur Recovery Unit, Hydrocracker, #2 Coker, #2 Crude
Cause: A loss of power to the Refinery's Boiler Instrumentation System caused the shutdown of the three plant boilers which generate the Refinery's 600 lb. steam. The loss of 600 lb. steam production caused upset conditions at a series of Refinery Process Units including the Sulfur Recovery Unit, Hydrocracker, #2 Coker and #2 Crude

Followup: No

Notes: The refinery has initiated an investigation into the cause of this incident. Based on the result of that investigation, measures will be taken in order to prevent a recurrence due to the same cause
326.0 pounds
78361

2005-04-19
K-401 (waste gas compressor number 2)
Cause: Waste gas compressor number 2 (K-401) automatically shut down, automatically diverting waste gas to the flare system.

Followup: No

Notes: Low-Sulfur content streams were routed to the flare to minimize sour gas flaring. Output was adjusted to minimize total amount of waste being sent to the flare. Same language about doing an investigation to understand the underlying cause and prevent future incidents.
3.0 pounds
78341

2005-04-17
K-401 (waste gas compressor number 2)
Cause: Waste gas compressor number 2 (K-401) automatically shut down, automatically diverting waste gas to the flare system.

Followup: No

Notes: Low-Sulfur content streams were routed to the flare to minimize sour gas flaring. Output was adjusted to minimize total amount of waste being sent to the flare.
2.0 pounds
78226

2005-04-13
K-401 (waste gas compressor number 2)
Cause: Waste gas compressor number 2 (K-401) automatically shut down, automatically diverting waste gas to the flare system.

Followup: No

Notes: Low-Sulfur content streams were routed to the flare to minimize sour gas flaring. Output was adjusted to minimize total amount of waste being sent to the flare. Letter rescinds report of nitric oxide because below reportable quantity.
7.0 pounds
05-BB005-157

2005-04-06
K-402 (Refinery waste gas compressor number 3)
Cause: K-402 unexpectedly shut down. Shortly after shutdown, refinery personnel identified the cause of the shutdown as a malfunction of the compressor motor ignition system.

Followup: No

Notes: The compressor motor was repaired and the compressor restarted, ending the incident.
108.0 pounds
77978

2005-04-02
No information given
Cause: From the verbal report:

Followup: No

Notes:
77936

2005-03-31
K-400 (Refinery waste gas compressor number 1)
Cause: Refinery waste gas compressor number 1 (K-400) unexpectedly shut down. Refinery waste gas automatically diverted to the flare system.

Followup: No

Notes: Adjustments made to the fuel/air mixture and K-400 restarted.
2.0 pounds
77659

2005-03-17
No information given
Cause: Waste gas compressor number 2 (K-401) automatically shut down due to a high temperature.

Followup: No

Notes: Letter rescinds verbal report because incident was not reportable. No release to atmosphere.
7.0 pounds
05-BB005-135

2005-03-13
C-2307 (Second Stage High-Pressure Separator) level controller; K-2303 (HCU Second Stage Recycle Compressor)
Cause: During maintenance, the Hydrocracker (HCU) Second Stage High-Pressure Separator (C-2307) level controller was inadvertently left in the manual position. Later, HCU Second Stage Recycle Compressor (K-2303) shut down due to high level in C-2307. Shutdown of K-2303 caused automatic depressurization of C-2307 to the refinery flare system.

Followup: No

Notes: Letter rescinds report of Sulfur Dioxide because below reportable quantity.
29.0 pounds
05-BB005-128

2005-03-02
Waste Gas Compressor Number 4 (K-406); Copper tubing connecting C-435 (first stage suction drum) to high-level instrumentation
Cause: Waste gas compressor number 4 (K-406) shut down due to failure of piece of copper tubing connecting C-435 to high-level shutdown instrumentation. When it failed, a false high level reading was recorded, causing automatic safety shutdown system to become engaged.

Followup: No

Notes: Low-Sulfur content streams were routed to the flare to minimize sour gas flaring. Output was adjusted to minimize amount sent to the flare. C-435 was retubed, K-406 was checked and restarted.
30.0 pounds
76869

2005-02-11
No information given
Cause: From the verbal report:

Followup: No

Notes:
6.0 pounds
05-BB005-113

2005-02-07
Unintended over pressurization of the Hydrocracker Light Ends Plant (HCU LEP) Depropanizer surge drum
Cause: Due to the isolation of the sight glass of the hydrocracker light ends plant depropanizer, the automatic level indication equipment was disabled and false reading was transmitted; this condition caused an unintended over pressurization of the HCU LEP Depropanizer surge drum, which was venter to the refinery flare system (No. 2 flare)

Followup: No

Notes: Refinery personnel evaluated the process operation, identified the source of the problem and made appropriate corrections, ending the incident.
90.0 pounds
05-BB005-106

2005-02-04
Electrical breaker G-457; Waste gas compressor number 2 (K-401)
Cause: Electrical breaker for G-457 malfunctioned. Waste gas compressor number 2 (K-401) shut down as a result of the electrical power outage and refinery waste gas was diverted to safety flare system.

Followup: No

Notes: Low-Sulfur content streams were routed to the flare to minimize sour gas flaring. Output was adjusted to minimize total amount of waste being sent to the flare. Note: the breaker for G-457 had been identified for repair and was supposed to be replaced that week.
13.0 pounds
05-BB005-105

2005-01-30
Pressure Safety Valve (PSV) on the Hydrocracker Light Ends Plant (LEP) A stripper as the source of the increased flame at number 2 flare
Cause: An abrupt increase in light material to the LEP A Stripper exceeded the tower overhead condenser cooling capacity, causing tower to overpressure.

Followup: No

Notes: After identifying the LEP A Stripper PSV flaring, lowered the pressure on the tower to end the incident.
15.0 pounds
05-BB005-100

2005-01-24
Waste gas compressor shut down and caused an over pressure situation
Cause: From the verbal report:

Followup: No

Notes:
8.0 pounds
05-BB005-93

2005-01-22
K-406 (waste gas compressor number 4)
Cause: Waste gas compressor number 4 (K-406) unexpectedly shut down. Waste gas was automatically diverted to refinery safety flare system.

Followup: No

Notes: Note: This compound was not included in the body of the letter. It was listed in a chart attached to the letter.
23.0 pounds
76362 & 76355

2005-01-21
Hydrocracker Light Ends Plant Butane Splitter Tower & LEP Depropanizer Tower Bottoms Flow Control Valve 50FC060
Cause: (1) 0600 hrs: Hydrocracker Light Ends Plant (LEP) Butane Splitter Tower began to overpressure because LEP Depropanizer Tower Bottoms Flow Control Valve (50FC060) had failed in the open position, letting propane to exit to the Butane Splitter. (2) 1700 hrs: Butane Splitter again began to overpressure due to the presence of propane. The level indication on the level instrument was detecting a false reading.

Followup: No

Notes: Letter speaks of two incidents on same day at 0600 hrs and 1700 hrs but attached report shows three incidents: (1) 4:05 a.m. lasting 3h 42m; (2) 3:15 p.m. lasting 41m; (3) 4:30 p.m. lasting 1h 25m. Amounts of compounds are only given in totals for all 3incidents.
75.1 pounds
76224

2005-01-18
No information given
Number 2 Flare -- Pressure Safety Valve (PSV) on Fuel Drum for Number 10 Boiler
Cause: From the verbal report:

Followup: No

Notes:
265.0 pounds
05-BB005-67

2005-01-06
K-406 (waste gas compressor number 4)
Cause: K-406 unexpectedly shut down and waste gas was automatically diverted to refinery safety flare system.

Followup: No

Notes: Sweet streams (lower Sulfur content) were routed to the flare to minimize sour gas flaring. Process unit output was adjusted in order to minimize the total amount of waste gas being sent to the flare. Shortly after shutdown, personnel re-started K-406 restoring the systems ability to process available refinery waste gas streams, ending the incident.
2.0 pounds
92464

2006-12-07
Lube Oil Cooler on Waste Gas Compressor K-406
Cause: leak in lube oil cooler tubing on WGC

Followup: No

Notes: Lube oil cooler on compressor was shut down. Leaking cooler tubing was repaired and all of the tubing was hydro-tested.
91726

2006-10-29
Flare
Cause: Compressor tripped and the safety valve on first-stage suction relieved to flare

Followup: Yes

Notes: DEQ report without corresponding letter from CRLLC
34.0 pounds
91667

2006-10-29
AE-AOA-05-0109 EPN 28 and 29
Cause: electrical switchgear failure.

Followup: No

Notes: DEQ report indicates that unknown amounts of the pollutants were released.
467.0 pounds
90530

2006-09-08
#1 Flare - AE-AOA-05-0109 EPN 28
Cause: during shutdown of GRU, gas had a higher BTU value than usual and the refinery furnaces automatically reduced the volume of gas consumed. The fuel drum was limited in its capacity to absorb fluctuationsin quality/auntity. The combination caused the fueldrum to vent excess pressure to the flare

Followup: No

Notes: CRLLC will evaluate prerequisites in GRU shutdown procedure.
14.0 pounds
90319

2006-08-29
No information given
Cause: No information given

Followup: No

Notes: Letter written to rescind notification of 8/29/06
1.0 pounds
90326

2006-08-29
#1 Flare - AE-AOA-05-0109 EPN 28
Cause: primary seal on recycle pump failed and resulted in venting to no. 1 flare. Later another primary seal failed

Followup: No

Notes: Spare Pump G-7913 was repaired and put in service, ending the incident. refinery has initiated an investigation into the cause
22.0 pounds
89293

2006-07-17
AE-AOA-05-0109 EPN 29
Cause: the process of startup and shutdown of the FCC resulting in apparent variability of FCC to Alky feedstock product quality with accumulation of noncondensable materials. Personnel allowed a controlled partial depressurization to avoid overpressure.

Followup: No

Notes: this incident will be reviewed by FCC and Alky process team leaders in order to increase awareness of the potential impacts of FCC shutdown/startup operations on Alky feed composition.
23.0 pounds
89266

2006-07-14
Flare
Cause: compressor shut down on the Hydrocracker Unit

Followup: No

Notes: Letter written to rescind notification of 7/14/6
2.0 pounds
89057

2006-07-06
No information given
Cause: No information given

Followup: No

Notes: Several pages missing from report!
88847

2006-06-23
Emergency Flare System - AE-AOA-05-0109 EPN 28
Cause: chiller malfunction. excess flare volume identified, search to identify source, as D9007 sphere as having relieved pressure to the emergency flare system. Sphere's chiller (ME9002) malfunctioned, heated up and overpressured.

Followup: No

Notes: sphere chiller was restarted which ended flaring.
19.0 pounds
89431

2006-06-21
#2 Flare AE-AOA-05-0109 EPN 29
Cause: alarm was improperly set allowing motor to operate above its design load leading to shut down of #1 Coker WGC

Followup: No

Notes: K-2800 high amperage alarm has been reset to 208 amps.
22.0 pounds
88694

2006-06-18
No information given
Cause: malfunction on fuel drum

Followup: No

Notes: Letter written to rescind notification of 6/18/6
88600

2006-06-14
#2 Flare - AE-AOA-05-0109 EPN 29
Cause: compressor shut down due to a low level reading in the lube Oil reservoir which was caused by the discharge of Oil from the west seal Oil trap to the refinery Oily water sewer system.

Followup: No

Notes: refinery has initiated an investigation into the cause
27.0 pounds
88492

2006-06-11
#2 Flare - AE-AOA-05-0109 EPN 29
Cause: thermal overload from direct sunlight, automatic shut down of WGC

Followup: No

Notes: temporary roof installed over the motor starter / thermal load protection system. This will prevent direct sunlight from contributing to excess temperature on the thermal over arm protection system.
29.0 pounds
88280

2006-06-02
No information given
Cause: malfunction in a control valve causes a clearing incident

Followup: No

Notes: DEQ report with no corresponding letter from CRLLC
8.0 pounds
87979

2006-05-19
Process unit
Cause: leak in a fan in a process unit

Followup: No

Notes: No information given
1.0 pounds
87763

2006-05-11
Flare
Cause: light ends sent to flare during start up

Followup: No

Notes: Letter written to rescind notification of 5/11/6
87256

2006-04-18
No information given
Cause: Cat Feed Hydrotreater Compressor tripped on overamp

Followup: No

Notes: Letter states that emissions were BRQ
7.0 pounds
86835

2006-03-29
AE-AOA-05-0109
Cause: Plant de-ethanizer tower (2410) relieved pressure to the emergency flare system after that propane treater (C7402) had plugged causing backpressure on the system leading to venting to emergency flare system. Release from Flare no. 2.

Followup: No

Notes: the refinery has initiated an investigation, appropriate measures will be taken in order to prevent a recurrence due to the same cause.
25.0 pounds
85953

2006-02-21
AE-AOA-05-0109
Cause: during startup of liquefied Petrol. Gas compressor, an unexpected liquid was present in the compressor discharge piping. This caused an unexpected upset resulting in over pressurization of the refinery fuel system. No. 2 Flare.

Followup: No

Notes: the refinery has initiated an investigation, appropriate measures will be taken in order to prevent a recurrence due to the same cause.
25.0 pounds
85641

2006-02-06
No information given
Cause: No information given

Followup: No

Notes: Letter written to rescind notification of 2/6/06
7.0 pounds
99870

2007-09-30
#2 Flare
Cause: pressure safety valve release

Followup: No

Notes: Letter states that no RQ's were exceeded